Arsenide nitride

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Cubic Mg3AsN, orthorhombic Ca3AsN Sr3AsN and Ba3AsN showing increased distortion as alkaline earth metal increases in size.

Arsenide nitrides or nitride arsenides are compounds containing anions composed of nitride (N3−) and arsenide (As3−). They can be considered as mixed anion compounds or mixed pnictide compounds. Related compounds include the arsenide phosphides, germanide arsenides, arsenide carbides, and phosphide nitrides.

Arsenide and nitride are quite different in size, so alloys are challenging to produce.[1] They can be produced by heating an arsenide compound with a nitride, under pressure so that nitrogen does not escape.

List

name formula crystal

system

space group unit cell Å volume density comment ref
Mg3AsN cubic Pm3m a =4.2148 Z=1 74.88 3.589 orange [2]
Ca3AsN orthorhombic Pbnm a=6.725 b=6.7198 c=9.5335 Z=4 430.8 3.237 red; moisture sensitive [3]
Ca14As6C0.445N1.135H4.915 P4/mbm a = 15.749 c = 9.1062 red; band gap 1.6 eV [4]
Cr3AsN tetragonal I4/mcm a=5.360 c=8.066 [5][6]
gallium arsenide nitride Ga(As,N)
indium gallium arsenide nitride (In,Ga)(As,N)
aluminium gallium arsenide nitride (Al,Ga)(As,N)
Sr3AsN orthorhombic Pbnm a=7.1856 b=10.1446 c=7.1464 Z=4 520.93 4.486 dark grey [2]
Ba3AsN orthorhombic Pbnm a=7.6741 b=10.7573 c=7.5387 Z=4 622.33 5.347 black [2]
LaFe2AsN orthorhombic Cmcm a =3.79932 b =11.11461 c =7.18656 303.474 [7]
LaCo2AsN orthorhombic Cmcm a =3.75993 b =11.1674 c =7.0185 294699 [7]
LaNi2AsN orthorhombic Cmcm a =3.71584 b =11.4147 c =6.9786 296.004 [7]
Th2ONAs P3m1 a=4.041 c=6.979 [8]
ThCrAsN metallic [9]
ThMnAsN tetragonal P4/nmm a =4.0818 b =4.0818 c =8.947 metallic [10]
ThFeAsN tetragonal P4/nmm a = 4.0367 c = 8.5262 superconductor Tc 30 K [11]
ThFe1-xCoxAsN superconductivity lost for x>0.05 [12]
ThNiAsN tetragonal P4/nmm a=4,0804 c=7.9888 superconductor at 4.3K [13]
BaTh2Fe4As4(N0.7O0.3)2 a=3.9886 c=29.853 Tc 22K [14]
U2N2As P3m1 a=3.833 c=6.737 [8]

References

  1. ^ Toivonen, J.; Oila, J.; Saarinen, K.; Hakkarainen, T.; Sopanen, M.; Lipsanen, H. (2002). "Vacancy-type defects in GaAsN grown by metalorganic vapor phase epitaxy". Conference Proceedings. 14th Indium Phosphide and Related Materials Conference (Cat. No.02CH37307). Stockholm, Sweden: IEEE. pp. 245–248. doi:10.1109/ICIPRM.2002.1014345. ISBN 978-0-7803-7320-4. S2CID 122733148.
  2. ^ a b c Stoiber, Dominik; Niewa, Rainer (2019-02-15). "Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba): Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba)". Zeitschrift für anorganische und allgemeine Chemie. 645 (3): 329–334. doi:10.1002/zaac.201800295. S2CID 219878132.
  3. ^ Chern, Ming Y.; Disalvo, F.J.; Parise, J.B.; Goldstone, Joyce A. (February 1992). "The structural distortion of the anti-perovskite nitride Ca3AsN". Journal of Solid State Chemistry. 96 (2): 426–435. Bibcode:1992JSSCh..96..426C. doi:10.1016/S0022-4596(05)80277-4.
  4. ^ Blankenship, Trevor V.; Wang, Xiaoping; Hoffmann, Christina; Latturner, Susan E. (2014-10-06). "LiCa 3 As 2 H and Ca 14 As 6 X 7 (X = C, H, N): Two New Arsenide Hydride Phases Grown from Ca/Li Metal Flux". Inorganic Chemistry. 53 (19): 10620–10626. doi:10.1021/ic501722d. ISSN 0020-1669. PMID 25222291.
  5. ^ Waki, Takeshi; Takao, Kenta; Tabata, Yoshikazu; Ohta, Hiroto; Yajima, Takeshi; Hiroi, Zenji; Nakamura, Hiroyuki (15 October 2017). "Possible Itinerant-Electron Canted Antiferromagnetism in Tetragonal Antiperovskite Cr 3 AsN". Journal of the Physical Society of Japan. 86 (10): 104706. Bibcode:2017JPSJ...86j4706W. doi:10.7566/JPSJ.86.104706.
  6. ^ Boller, H. (1968). "Komplexcarbide und-nitride mit aufgefülltem U3Si-Typ". Monatshefte für Chemie. 99 (6): 2444–2449. doi:10.1007/BF01154362. S2CID 97266394.
  7. ^ a b c Jeong, Sehoon; Matsuishi, Satoru; Bang, Joonho; Hosono, Hideo (2015-04-01). "Crystal structure and physical properties of new transition metal based pnictide compounds: La TM 2AsN ( TM = Fe, Co, and Ni)". APL Materials. 3 (4): 041509. Bibcode:2015APLM....3d1509J. doi:10.1063/1.4913395. ISSN 2166-532X.
  8. ^ a b Benz, R.; Zachariasen, W. H. (1969-02-15). "Crystal structure of the compounds U2N2X and Th2(N,O)2 with X = P, S, As and Se". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 25 (2): 294–296. doi:10.1107/S0567740869002135.
  9. ^ Wang, Zhi-Cheng; Shao, Ye-Ting; Lin, Yi-Qiang; Song, Shi-Jie; Li, Bai-Zhuo; Cheng, Er-Jian; Li, Shi-Yan; Zhu, Qin-Qing; Ren, Zhi; Cao, Guang-Han (2023-08-09). "Absence of superconductivity in electron-doped chromium pnictides ThCrAsN 1 − x O x". Physical Review B. 108 (6): 064503. arXiv:2308.05267. Bibcode:2023PhRvB.108f4503W. doi:10.1103/PhysRevB.108.064503. ISSN 2469-9950. S2CID 260775924.
  10. ^ Zhang, Fuxiang; Li, Baizhuo; Ren, Qingyong; Mao, Huican; Xia, Yuanhua; Hu, Bingfeng; Liu, Zichen; Wang, Zhicheng; Shao, Yeting; Feng, Zhifa; Tan, Shugang; Sun, Yuping; Ren, Zhi; Jing, Qiang; Liu, Bo (2020-03-02). "ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects". Inorganic Chemistry. 59 (5): 2937–2944. doi:10.1021/acs.inorgchem.9b03294. ISSN 0020-1669. PMID 32064866. S2CID 211133783.
  11. ^ Wang, Cao; Wang, Zhi-Cheng; Mei, Yu-Xue; Li, Yu-Ke; Li, Lin; Tang, Zhang-Tu; Liu, Yi; Zhang, Pan; Zhai, Hui-Fei; Xu, Zhu-An; Cao, Guang-Han (2016-02-24). "A New ZrCuSiAs-Type Superconductor: ThFeAsN". Journal of the American Chemical Society. 138 (7): 2170–2173. arXiv:1603.01501. doi:10.1021/jacs.6b00236. ISSN 0002-7863. PMID 26853632. S2CID 5393656.
  12. ^ Wang, Jingfeng; Jiao, Fei; Wang, Xianyu; Zhu, Shu; Cai, Lingbo; Yang, Chunhui; Song, Pengwei; Zhang, Fuxiang; Li, Baizhuo; Li, Yunlong; Hu, Jiayuan; Li, Shubin; Li, Yuqiang; Tan, Shugang; Mei, Yuxue (2020-07-21). "The phase transition of ThFe 1-x Co x AsN from superconductor to metallic paramagnet". EPL (Europhysics Letters). 130 (6): 67003. Bibcode:2020EL....13067003W. doi:10.1209/0295-5075/130/67003. ISSN 1286-4854. S2CID 225558397.
  13. ^ Wang, Zhi-Cheng; Shao, Ye-Ting; Wang, Cao; Wang, Zhen; Xu, Zhu-An; Cao, Guang-Han (2017-06-01). "Enhanced superconductivity in ThNiAsN". EPL (Europhysics Letters). 118 (5): 57004. Bibcode:2017EL....11857004W. doi:10.1209/0295-5075/118/57004. ISSN 0295-5075. S2CID 125752599.
  14. ^ Shao, Ye-Ting; Wang, Zhi-Cheng; Li, Bai-Zhuo; Wu, Si-Qi; Wu, Ji-Feng; Ren, Zhi; Qiu, Su-Wen; Rao, Can; Wang, Cao; Cao, Guang-Han (September 2019). "BaTh$_2$Fe$_4$As$_4$(N$_{0.7}$O$_{0.3}$)$_2$: An Iron-Based Superconductor Stabilized by Inter-Block-Layer Charge Transfer". Science China Materials. 62 (9): 1357–1362. arXiv:1908.03992. doi:10.1007/s40843-019-9438-7. ISSN 2095-8226. S2CID 164224680.
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