Wikipedia:Files for deletion/2011 December 16
December 16
File:Burgessreagent.gif + 21 others
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The result of the discussion was: Delete. -FASTILY (TALK) 05:27, 24 December 2011 (UTC)[reply]
- File:Burgessreagent.gif (delete | talk | history | links | logs) – uploaded by V8rik (notify | contribs | uploads | upload log).
- File:Boroncaronitrides.gif (delete | talk | history | links | logs) – uploaded by V8rik (notify | contribs | uploads | upload log).
- File:Borazine carbene.gif (delete | talk | history | links | logs) – uploaded by V8rik (notify | contribs | uploads | upload log).
- File:Bisulfitereaction.gif (delete | talk | history | links | logs) – uploaded by V8rik (notify | contribs | uploads | upload log).
- File:Bisulfite adduct.gif (delete | talk | history | links | logs) – uploaded by V8rik (notify | contribs | uploads | upload log).
- File:Plantstanolester PSE.jpg (delete | talk | history | links | logs) – uploaded by Truikka (notify | contribs | uploads | upload log).
- File:Phosphatidylinositol-3-phosphate.jpg (delete | talk | history | links | logs) – uploaded by Jagowins (notify | contribs | uploads | upload log).
- File:Phosphatidylinositol-3,4-bisphosphate.jpg (delete | talk | history | links | logs) – uploaded by Jagowins (notify | contribs | uploads | upload log).
- File:Phosphatidylinositol-3,4,5-trisphosphate.jpg (delete | talk | history | links | logs) – uploaded by Jagowins (notify | contribs | uploads | upload log).
- File:Gcp2-naag-version2.jpg (delete | talk | history | links | logs) – uploaded by Marcxanderson (notify | contribs | uploads | upload log).
- File:Monomer route to parylene AF-4.jpg (delete | talk | history | links | logs) – uploaded by Senkej (notify | contribs | uploads | upload log).
- File:Parylene X repeat unit.jpg (delete | talk | history | links | logs) – uploaded by Senkej (notify | contribs | uploads | upload log).
- File:Parylene N repeat unit.jpg (delete | talk | history | links | logs) – uploaded by Senkej (notify | contribs | uploads | upload log).
- File:Parylene C repeat unit.jpg (delete | talk | history | links | logs) – uploaded by Senkej (notify | contribs | uploads | upload log).
- File:Ortho resonance.JPG (delete | talk | history | links | logs) – uploaded by Montano336 (notify | contribs | uploads | upload log).
- File:NMO example.gif (delete | talk | history | links | logs) – uploaded by V8rik (notify | contribs | uploads | upload log).
- File:MolecularTweezerEmpl1.gif (delete | talk | history | links | logs) – uploaded by V8rik (notify | contribs | uploads | upload log).
- File:Magnolol purification.jpg (delete | talk | history | links | logs) – uploaded by Benbeel (notify | contribs | uploads | upload log).
- File:SerThrCys-pPro.jpg (delete | talk | history | links | logs) – uploaded by Kosigrim (notify | contribs | uploads | upload log).
- File:Statin.JPG (delete | talk | history | links | logs) – uploaded by Thormog (notify | contribs | uploads | upload log).
- File:Statin final.JPG (delete | talk | history | links | logs) – uploaded by Thormog (notify | contribs | uploads | upload log).
- File:Otera's catalyst.JPG (delete | talk | history | links | logs) – uploaded by Yidele (notify | contribs | uploads | upload log).
Orphaned file, replaced by svg, no need to keep any more. Ronhjones (Talk) 00:18, 16 December 2011 (UTC)[reply]
- Comments – re: Burgess Reagant image, the original shows an –OMe group in the product which has been changed to –O–CH2; this is incorrect and should be corrected to –O–CH3. EdChem (talk) 09:43, 19 December 2011 (UTC)[reply]
- re: Borazine carbene image, the intermediate in the SVG shows a carbon radical, which is incorrect. The original file correctly shows a carbocation. The radical dot on the intermediate on the SVG file should be changed to a '+' charge. EdChem (talk) 09:51, 19 December 2011 (UTC)[reply]
- re: Phosphatidylinositol-3,4,5-trisphosphate image, the phosphate group at the 5' position is deprotonated in the original image but protonated in the replacement SVG image. EdChem (talk) 10:08, 19 December 2011 (UTC)[reply]
- re: Gcp2-naag-version2 image, the original image correctly italicises the N's in N-acetyl and N-acetylaspartate; the replacement SVG has these N's unitalicised and this should be corrected. EdChem (talk) 10:20, 19 December 2011 (UTC)[reply]
- Fixed Burgess, Borazine, Phosphatidylinositol and Gcps Louisajb (talk) 12:55, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Grace 1064.jpg (delete | talk | history | links | logs) – uploaded by GRS4 (notify | contribs | uploads | upload log).
Orphaned File, Unencyclopaedic, no use to keep Ronhjones (Talk) 01:38, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Grad usmantariq.jpg (delete | talk | history | links | logs) – uploaded by Usman one (notify | contribs | uploads | upload log).
Unused user photo WP:NOTHOST Ronhjones (Talk) 01:41, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Hamilton Fish Brady.jpg (delete | talk | history | links | logs) – uploaded by Cmguy777 (notify | contribs | uploads | upload log).
Orphaned, superseded by File:Hamilton Fish Brady Edited.jpg (this one appears to have the same edits done as on the "edited" version - when compared to the original you can see that this one has also had the black marks removed etc.) Calliopejen1 (talk) 04:34, 16 December 2011 (UTC)[reply]
- I do not mind the deletion; however, you can examine the File: Hamilton Fish Brady.jpg. On the top of Fish's forehead are some markings. On the "edited" version the top forehead on the hair line has been edited more naturally without signifigant markings. You can delete the Hamilton Fish Brady.jpg photo, but please keep the "edited" version in the article. Thanks. Cmguy777 (talk) 05:44, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Hare.png (delete | talk | history | links | logs) – uploaded by Bwemerson (notify | contribs | uploads | upload log).
Orphaned, Low quality Calliopejen1 (talk) 04:48, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Hardware Design Engineering Team.jpg (delete | talk | history | links | logs) – uploaded by Kennzeichnen (notify | contribs | uploads | upload log).
Orphaned, Unencyclopedic Calliopejen1 (talk) 04:48, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Hardware Design Engineering CEDSG.jpg (delete | talk | history | links | logs) – uploaded by Kennzeichnen (notify | contribs | uploads | upload log).
Orphaned, Unencyclopedic Calliopejen1 (talk) 04:48, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Lake Danao Park.jpg (delete | talk | history | links | logs) – uploaded by Kennzeichnen (notify | contribs | uploads | upload log).
Orphaned, Unencyclopedic Calliopejen1 (talk) 04:48, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Green Lake Park.jpg (delete | talk | history | links | logs) – uploaded by Kennzeichnen (notify | contribs | uploads | upload log).
Orphaned, Unencyclopedic Calliopejen1 (talk) 04:48, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Green Lake Parke.jpg (delete | talk | history | links | logs) – uploaded by Kennzeichnen (notify | contribs | uploads | upload log).
Orphaned, Unencyclopedic Calliopejen1 (talk) 04:49, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Mark Anthony Maranga.jpg (delete | talk | history | links | logs) – uploaded by Kennzeichnen (notify | contribs | uploads | upload log).
Orphaned, Unencyclopedic Calliopejen1 (talk) 04:49, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Hanko dot.png (delete | talk | history | links | logs) – uploaded by Janke (notify | contribs | uploads | upload log).
Orphaned, superseded by standard locator map Calliopejen1 (talk) 04:49, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Hanko coat of arms.png (delete | talk | history | links | logs) – uploaded by Lamaer (notify | contribs | uploads | upload log).
Orphaned, no source, superseded by File:Hanko.vaakuna.svg Calliopejen1 (talk) 04:50, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:01, 21 December 2011 (UTC)[reply]
- File:Hanged irish piper.jpg (delete | talk | history | links | logs) – uploaded by Gold_heart (notify | contribs | uploads | upload log).
Orphaned, Low quality, unverifiable source Calliopejen1 (talk) 04:50, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Hang loose.jpg (delete | talk | history | links | logs) – uploaded by London_Reports (notify | contribs | uploads | upload log).
Orphaned, Unencyclopedic Calliopejen1 (talk) 04:51, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Handyirving.jpg (delete | talk | history | links | logs) – uploaded by Stilltim (notify | contribs | uploads | upload log).
Orphaned crop of File:Levin Handy.jpg Calliopejen1 (talk) 04:52, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Hangu Romania.png (delete | talk | history | links | logs) – uploaded by Daqy (notify | contribs | uploads | upload log).
Orphaned, superseded by standard locator map Calliopejen1 (talk) 04:56, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Map=coat Hangu Romania.png (delete | talk | history | links | logs) – uploaded by Daqy (notify | contribs | uploads | upload log).
Orphaned, Unencyclopedic Calliopejen1 (talk) 04:56, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Polyanhydride structure.jpg (delete | talk | history | links | logs) – uploaded by Mmbyron (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 06:57, 16 December 2011 (UTC)[reply]
- Comment - the SVG version is clearly superior so the JPG file should be deleted, but the SVG could also be improved by italicising the n and removing the "R group" label, unless someone can explain what the label is supposed to mean. As it stands, polyanhydride structure, which contains an R group, appears to be being labelled as an R group, which is a recursive definition, hence my confusion. EdChem (talk) 04:00, 17 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:SMasemech.GIF (delete | talk | history | links | logs) – uploaded by Allysonmcloed 2009 (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:00, 16 December 2011 (UTC)[reply]
- Delete but replacement has fishhooks instead of full-arrows in several mechanistic steps. DMacks (talk) 08:35, 16 December 2011 (UTC)[reply]
- Comment – both replacement and original have issues needing correction, inlcuding:
- An arrow begins from the bond between an R group and a carbonyl group and goes to nowhere, yet seems not to mean anything – it should be removed
- Changing the carboxylic acid to HA is unclear to those unfamiliar with organic chemistry
- Labelling three potentially different groups as R is bad practice, it should be R, R', and R'' or similar (like R1, R2, and R3)
- The arrow from the phosporous–oxygen bond to the H atom of HA looks like it is forming a P—H bond; moving the HA to above the chain and curving arrow the other way would look much more like forming the new O—H bond
- The second arrow should have −A− adjacent to it, or the A− product should be shown
- None of the arrows should be fish-hooks, as DMacks has noted
- EdChem (talk) 08:08, 19 December 2011 (UTC)[reply]
I have found another mechanism, a basic one from a book and uploaded this as SMasemech2.svg - have a look at this and see if it is better/worse? It is a general mechanistic outlineLouisajb (talk) 10:55, 19 December 2011 (UTC)[reply]
- In the new image, the double bonds in the aromatic ring disappear and then re-appear. The mechanism omits the deprotonation of the aromatic nitrogen and the protonation of the alkoxy anion. Such short-cuts are likely to confuse readers, and are (IMO) bad practice when used in books. Sorry to be picky but its hard enough getting students to understand mechanistic organic chemistry and I don't like book or online sources that don't follow the strict rules of this notational formalism. EdChem (talk) 11:54, 19 December 2011 (UTC)[reply]
- Then it would be best to just replace the old one and let someone else have a go. I have looked through my books and on the internet and can't get a suitable alternative. The original was suitable for long enough so it might as well go back. Louisajb (talk) 12:31, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Secondaryradicalneucleophilicdetermination.jpg (delete | talk | history | links | logs) – uploaded by Unimaginatively (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:01, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Nine diferulic acid structures.gif (delete | talk | history | links | logs) – uploaded by Terri G (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:02, 16 December 2011 (UTC)[reply]
- Comment - the top left structure, 8,8'-DIFA, has a methyl group attached to the second benzene ring but on the original file this is a methoxy group. Based on the formula given for the diferulic acids in their wiki-article, I believe that the original file is correct. This should be fixed before the low quality GIF is deleted. EdChem (talk) 17:12, 17 December 2011 (UTC)[reply]
- Fixed Louisajb (talk) 11:01, 19 December 2011 (UTC)[reply]
- Thanks. EdChem (talk) 11:47, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Oxindole 2.gif (delete | talk | history | links | logs) – uploaded by Hakons (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:03, 16 December 2011 (UTC)[reply]
- Support - SVG version is far superior, no reason to keep or use the low quality GIF. EdChem (talk) 02:36, 17 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:PDP 2.gif (delete | talk | history | links | logs) – uploaded by Hakons (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:04, 16 December 2011 (UTC)[reply]
- Delete per nom, but replacement exchanges pixelation and weird angles for a "CH3" that is overlapping an adjacent bond. DMacks (talk) 08:28, 16 December 2011 (UTC)[reply]
- Fixed Louisajb (talk) 11:08, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:E1cB.gif (delete | talk | history | links | logs) – uploaded by V8rik (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:04, 16 December 2011 (UTC)[reply]
- Delete as low-quality. But now that we have a high quality, it's more obvious both are incorrect (anionic elimination would have an anionic L– as product not L• radical, and the mechanistic arrow leading to it looks single-electron also). DMacks (talk) 08:26, 16 December 2011 (UTC)[reply]
- Comment - DMacks is correct, both the original and the improved SVG versions are incorrect as they both fail to conserve charge. I suggest the following modifications:
- In the original diagram, move the lone pair on the B to the other side as the arrow should start at the lone pair - otherwise there would be no reason to include it
- I realise that it is not easy to do, but the arrow forming the carbanion should begin at the centre of the carbon-hydrogen bond, not at the H atom
- The resulting protonated base species should be charged, ie. BH+ not BH. The positive charge should be shown on the B atom. Without this charge, there is the spontaneous creation of a negative charge on the carbanion without a counter-balancing positive charge
- The arrow forming the double bond should begin at the carbanion negative charge and not originate in a carbon-carbon bond
- The arrow for the leaving group leaving should be double-headed, and the leaving group should be an anion L- and not a radical
- Sorry to be so picky but this is a fundamental and prototypical organic transformation and the WP exemplar for it should be absolutely accurate. EdChem (talk) 02:34, 17 December 2011 (UTC)[reply]
- I have uploaded an alternative version of the Elimination Reaction E1, which corresponds to textbooks and internet sites where the Leaving Group (in this case X) leaves in the first step to create the cation and then the B: comes in and removes the H to give the alkene. It is called E1cB2.svg (http://en.wikipedia.org/wiki/File:E1cB2.svg). See what you think if you would prefer this as the alternative. Louisajb (talk) 11:36, 19 December 2011 (UTC)[reply]
- Sorry, but that is incorrect. The new file gives an E1 elimination with a carbocation intermediate. The original file is an E1cb (or sometimes Ecb1) elinmiation with a carbanion intermediate. These are two different elimination processes. EdChem (talk) 11:47, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Dimer route to parylene AF-4.jpg (delete | talk | history | links | logs) – uploaded by Senkej (notify | contribs | uploads | upload log).
Orphaned file, poor quality, replaced by SVG. Leyo 07:05, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Pde5 dd fig4.gif (delete | talk | history | links | logs) – uploaded by Reynirsc (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:06, 16 December 2011 (UTC)[reply]
- Delete - replacement looks fine. EdChem (talk) 08:14, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Nevirapine-wing.jpg (delete | talk | history | links | logs) – uploaded by Aslimarati (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:07, 16 December 2011 (UTC)[reply]
- Comment – not sure why the bonds off the wing II pyridine ring are shown as above the plane when the geometry is planar. I also suspect this could be clearer (and more useful to other wikis) if labels were removed and the wings indicated by colours. If the nevirapine label is retained, it should not be capitalised. Having said all that, the SVG is clearly better than the JPG image it is meant to replace, so I support deletion of the JPG. EdChem (talk) 08:20, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Metabolites of Chlorpromazine.JPG (delete | talk | history | links | logs) – uploaded by Opsophagos (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:08, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Didemnins.JPG (delete | talk | history | links | logs) – uploaded by Numero4 (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:09, 16 December 2011 (UTC)[reply]
- Delete low quality original version, replacement SVG is superior. EdChem (talk) 08:24, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Lebedev reaction.png (delete | talk | history | links | logs) – uploaded by Mets501 (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:12, 16 December 2011 (UTC)[reply]
- Comment - the equation as written implies a spontaneous reaction of ethanol to 1,3-butadiene. I suggest a much longer reaction arrow with "metal oxide catalyst" or some similar comment above the arrow, and perhaps some indication of conditions (temperature and/or pressure) below the arrow. The paper from which this comes will provide the necessary information - I can find it if needs be - but as a matter of general practice I believe WP should not show equations for non-spontaneous reactions at RTP without some indication of any needed catalysts and conditions, etc. EdChem (talk) 02:10, 17 December 2011 (UTC)[reply]
- I prefer to have as little text as possible in the image and to specify condidtions in the caption. The usability in all languange versions of Wikipedia is one advantage, the focus on the reaction itself is another. --Leyo 10:51, 17 December 2011 (UTC)[reply]
- Fair point, but if the paper referenced indicates what the metal oxide was we could simply use its formula. EdChem (talk) 11:12, 17 December 2011 (UTC)[reply]
- PS: I don't agree with omitting conditions, but removing names and avoiding words for greater inter-wiki applicability makes good sense. EdChem (talk) 08:36, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Cocaine Stereoisomers.PNG (delete | talk | history | links | logs) – uploaded by Nagelfar (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 07:14, 16 December 2011 (UTC)[reply]
- Delete as copyvio (cut'n'paste derivative of published journal article--see my comments on uploader's talkpage). But replacement is not typographically correct (italics for R/S designators). DMacks (talk) 08:31, 16 December 2011 (UTC)[reply]
- The problem has been addressed in File:Cocaine Stereoisomers3.svg. --Leyo 10:11, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:UA(2S)-GlcNS(6S).png (delete | talk | history | links | logs) – uploaded by K.murphy (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 10:10, 16 December 2011 (UTC)[reply]
- Comment – both the original and the replacement have a − charge missing from the O atom of the —CH2—O group on the substituted glucose ring. Otherwise, the SVG version is better than the PNG it was made to replace. EdChem (talk) 08:33, 19 December 2011 (UTC)[reply]
- Fixed Louisajb (talk) 11:43, 19 December 2011 (UTC)[reply]
- Thanks, I now support deletion of the original PNG file. EdChem (talk) 11:57, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Catcechol-Quinone.GIF (delete | talk | history | links | logs) – uploaded by Shashank Shekhar (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 10:12, 16 December 2011 (UTC)[reply]
- Delete but arrow is wrong (should be single "synthesis reaction" not double "retrosynthesis"). DMacks (talk) 14:35, 16 December 2011 (UTC)[reply]
- Comment - I suggest that the SVG be altered to specify that the product is o-benzoquinone or 1,2-benzoquinone. Simply "benzoquinone" is imprecise as it could refer to p-benzoquinone. Also, chemical names (including the catechol oxidase enzyme over the reaction arrow) are not proper nouns and so should not be capitalised unless they begin a sentence. Thus, I suggest the labels be "catechol", "catechol oxidase", and "o-benzoquinone". However, even if these changes are not made, the SVG version is superior to the GIF version and so deletion of the GIF is justified.
- The arrow was fixed by the uploader. Concerning the labels, I would just remove “Catechol” and “Benzoquinone”. If necessary, the substance names can be added in the image caption in the article. --Leyo 11:01, 17 December 2011 (UTC)[reply]
- Removing the names and including them in the caption seems sensible to me. EdChem (talk) 08:34, 19 December 2011 (UTC)[reply]
- The arrow was fixed by the uploader. Concerning the labels, I would just remove “Catechol” and “Benzoquinone”. If necessary, the substance names can be added in the image caption in the article. --Leyo 11:01, 17 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Nc outline.gif (delete | talk | history | links | logs) – uploaded by KTM Jared 683 (notify | contribs | uploads | upload log).
Unidentified logo, Orphan image, without further information , potential for usage minimal. Sfan00 IMG (talk) 12:14, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:ConjugatedAdditionofThiols.gif (delete | talk | history | links | logs) – uploaded by V8rik (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 12:50, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted as F8 by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) A file with this name on Commons is now visible. AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:EnantioselectiveOrganoCascadeCatalysis .gif (delete | talk | history | links | logs) – uploaded by V8rik (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 12:51, 16 December 2011 (UTC)[reply]
- Oppose. Replacement has arrows that are substantially half-arrow fish-hook (correct is electron-pair full-arrow--even original has more of these "correct" and others blurry; .svg is wrong) and the perchlorophenol is so close to the t-butyl in the lower-center intermediate that it appears bonded. DMacks (talk) 14:39, 16 December 2011 (UTC)[reply]
- Oppose - .svg image is incorrect in that arrows are missing. For example, there should be an arrow from the oxygen lone pair in the furan ring in the second step to form the oxonium species. An arrow from the nitrogen lone pair in step four is also missing. Both of these are included in the original. The trifluoroacetic acid is also deprotonated and the trifluoroacetate ion reprotonated without explanation, leading to violation of the law of conservation of charge. The original isn't totally correct but it is more accurate than the .svg image. EdChem (talk) 21:33, 16 December 2011 (UTC)[reply]
- The author of the SVG version, Louisajb, might be able to address the comments soon. --Leyo 21:41, 16 December 2011 (UTC)[reply]
- I have added the missing arrows present in the first one. FYI - I am copying the original pictures as they were and not correcting any missing chemistry. The originals were on Wikipedia for long enough without being altered or removed. So if someone else wants to redraw them for more accurate chemistry, then they are welcome to do that. I am merely improving the aesthetic quality of the original drawings. Louisajb (talk) 10:12, 19 December 2011 (UTC)[reply]
- In the new version, the N atom in second structure and the O atom in the third appear to bear radical dots; these should be positive charges, as in the original (sorry if I missed this before). As for not correcting the chemistry, I can understand leaving it if you aren't sure - and the aesthetic improvements are welcome, please let me be clear about that - but if you are sure there are errors, they are worth correcting, or at least asking about. Regards, EdChem (talk) 12:08, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Mitomycin c tailoring.gif (delete | talk | history | links | logs) – uploaded by Bwalkowicz (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 12:52, 16 December 2011 (UTC)[reply]
- Comment – both the original and the replacement have errors. The replacement has lost the negative charge that should be on the –OPO3H group of the C4P. The following alterations should also be made to the final product:
- the C–C bond between C(6) and C(7) should be a double bond
- the C–O bonds at C(5) and C(8) should be double bonds and not end in radicals
- the C–C bond between C(1) and C(9a) should be in blue not black
- The original also included numbering of the C atoms; retaining this in one of the diagrams (core or final product) would help in making clear the description which precedes the diagram in the mitomycin article. EdChem (talk) 09:20, 19 December 2011 (UTC)[reply]
- Fixed Louisajb (talk) 12:05, 19 December 2011 (UTC)[reply]
- Much better, thanks. EdChem (talk) 12:10, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Mitomycin c AHBA.gif (delete | talk | history | links | logs) – uploaded by Bwalkowicz (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 12:53, 16 December 2011 (UTC)[reply]
- Comment – all three HO3PO– groups in the original file correctly show a negative charge but these have disappeared on the SVG version. These charges should be re-inserted before the SVG replaces the low quality gif file. EdChem (talk) 08:55, 19 December 2011 (UTC)[reply]
- Fixed Louisajb (talk) 12:09, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 25 December 2011 (UTC)[reply]
- File:PDSp.gif (delete | talk | history | links | logs) – uploaded by Nblair11285 (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 12:54, 16 December 2011 (UTC)[reply]
- Oppose There is a stray "3" in the proposed replacement. DMacks (talk) 14:42, 16 December 2011 (UTC)[reply]
- Thanks for spotting it. I notified the uploader of the SVG version. This flaw can easily be fixed. --Leyo 15:16, 16 December 2011 (UTC)[reply]
- Fixed the stray 3 in the replacement Louisajb (talk) 15:48, 16 December 2011 (UTC)[reply]
- Quibbles – there should be a space between numbers and units, so 15 mol% not 15mol%, and the unit for hours is h, so 24 h not 24hr, but these are minor and the SVG is clearly preferable to the GIF version. EdChem (talk) 08:46, 19 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Dimer Resveratrol Structure.jpg (delete | talk | history | links | logs) – uploaded by Dygun (notify | contribs | uploads | upload log).
Orphaned file, low quality, replaced by SVG. Leyo 12:55, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Harta Tomsani.jpg (delete | talk | history | links | logs) – uploaded by After_Shock (notify | contribs | uploads | upload log).
Orphaned, source is an unspecified "old map" (doesn't look that old anyways) - likely copyvio Calliopejen1 (talk) 17:29, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Harvard Logo.png (delete | talk | history | links | logs) – uploaded by Meganfoxx (notify | contribs | uploads | upload log).
Orphaned, not sure why this would be needed, the background behind the text may not be {{PD-text}} Calliopejen1 (talk) 17:31, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:HarveyFamily1948.jpg (delete | talk | history | links | logs) – uploaded by Bdow1722 (notify | contribs | uploads | upload log).
Orphaned, in the public domain in Australia but not in the public domain in the US as required (1948 image would have been PD in australia in 1998, but key URAA date is 1996. since it wasn't public domain in home country as of 1996, it's still copyrighted in the us because the normal pre-1923 rule applies.) Calliopejen1 (talk) 17:36, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Harry Moniba.jpg (delete | talk | history | links | logs) – uploaded by Chris_brown_444 (notify | contribs | uploads | upload log).
Dubious self-made image Calliopejen1 (talk) 17:39, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:B (5).JPG (delete | talk | history | links | logs) – uploaded by Omreg88 (notify | contribs | uploads | upload log).
Orphaned, Unencyclopedic (dead bird?) Calliopejen1 (talk) 17:46, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:B Circuit.png (delete | talk | history | links | logs) – uploaded by RTC (notify | contribs | uploads | upload log).
Orphaned, superseded by File:C Battery circuit of a Triode vacuum tube.png Calliopejen1 (talk) 17:51, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:B mitchell.jpg (delete | talk | history | links | logs) – uploaded by Mitchellhcf01 (notify | contribs | uploads | upload log).
Orphaned, Unencyclopedic Calliopejen1 (talk) 17:52, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:B Puzzle colours.png (delete | talk | history | links | logs) – uploaded by Ouro (notify | contribs | uploads | upload log).
Orphaned, Unencyclopedic Calliopejen1 (talk) 17:53, 16 December 2011 (UTC)[reply]
- Comment from original uploader I'm okay with it being deleted if it's orphaned and not required. I actually forgot all about it. --Ouro (blah blah) 18:10, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Veluthampi.jpg (delete | talk | history | links | logs) – uploaded by Manu_rocks (notify | contribs | uploads | upload log).
no source, doesn't really look like a photograph (so the lenient PD-India rule for photos doesn't apply) Calliopejen1 (talk) 18:03, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Scranton, PA sign IMG 1524.JPG (delete | talk | history | links | logs) – uploaded by Billy Hathorn (notify | contribs | uploads | upload log).
Unused. Probably also a derivative work. MGA73 (talk) 20:53, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Billy the Kid statue in Hico, TX Picture 2242.jpg (delete | talk | history | links | logs) – uploaded by Billy Hathorn (notify | contribs | uploads | upload log).
No FOP in the US for statues. MGA73 (talk) 20:57, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Troops saluted in Eagle Pass, TX IMG 1921.JPG (delete | talk | history | links | logs) – uploaded by Billy Hathorn (notify | contribs | uploads | upload log).
Unused. Probably also an unfree derivative work (no FOP - not a building) MGA73 (talk) 21:05, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Western mural in Laredo, TX IMG 1814.JPG (delete | talk | history | links | logs) – uploaded by Billy Hathorn (notify | contribs | uploads | upload log).
Unused. Proably also an unfree mural. MGA73 (talk) 21:07, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:911 Mural in Laredo, TX IMG 1822.JPG (delete | talk | history | links | logs) – uploaded by Billy Hathorn (notify | contribs | uploads | upload log).
Unused. Probably also an unfree mural. MGA73 (talk) 21:08, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Hico mural IMG 0751.JPG (delete | talk | history | links | logs) – uploaded by Billy Hathorn (notify | contribs | uploads | upload log).
No FOP in the US for murals. MGA73 (talk) 21:15, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Rabbit IMG 0312.JPG (delete | talk | history | links | logs) – uploaded by Billy Hathorn (notify | contribs | uploads | upload log).
Unused. Also no FOP in the US for statues. MGA73 (talk) 21:16, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Crockett 07-02-2008 08;45;03PM.JPG (delete | talk | history | links | logs) – uploaded by Billy Hathorn (notify | contribs | uploads | upload log).
Unused. Also no FOP in the US for statues so it is not sure it is free. MGA73 (talk) 21:17, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Dusty Rhodes exhibit IMG 0007.JPG (delete | talk | history | links | logs) – uploaded by Billy Hathorn (notify | contribs | uploads | upload log).
Derivative work. No FOP (not a building). MGA73 (talk) 21:20, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 02:02, 24 December 2011 (UTC)[reply]
- File:Grand Entrance leading up to clarence ballroom.jpg (delete | talk | history | links | logs) – uploaded by Marquisofqueensbury (notify | contribs | uploads | upload log).
Orphaned File, Unencyclopaedic, no use to keep Ronhjones (Talk) 22:12, 16 December 2011 (UTC)[reply]
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The result of the discussion was: Keep. -FASTILY (TALK) 05:33, 24 December 2011 (UTC)[reply]
- File:5000 Lebanese Pounds Obverse.jpg (delete | talk | history | links | logs) – uploaded by Gilly 54 (notify | contribs | uploads | upload log).
No information given about copyright status of Lebanese currency (which I haven't found), only a claim that photo is under Creative Commons license. —innotata 23:19, 16 December 2011 (UTC)[reply]
- Keep and tag non-free if necessary. I believe that it's our common practice that it is okay to have non-free currency exemplars in articles about the currency. Calliopejen1 (talk) 17:41, 18 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted as F8 by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) A file with this name on Commons is now visible. AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Gravedulino.jpg (delete | talk | history | links | logs) – uploaded by Kanadanino (notify | contribs | uploads | upload log).
Orphaned File, Unknown Subject, no use to keep Ronhjones (Talk) 23:37, 16 December 2011 (UTC)[reply]
- Keep I think this could be a useful representation of pregnancy. Face blacked out, so there really aren't any privacy issues either. Calliopejen1 (talk) 17:40, 18 December 2011 (UTC)[reply]
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The result of the discussion was: Delete; deleted by Fastily (talk · contribs · blocks · protections · deletions · page moves · rights · RfA) AnomieBOT⚡ 07:04, 24 December 2011 (UTC)[reply]
- File:Gray langurs garhwal2008b.jpg (delete | talk | history | links | logs) – uploaded by Fowler&fowler (notify | contribs | uploads | upload log).
Orphan file, poor focus Ronhjones (Talk) 23:45, 16 December 2011 (UTC)[reply]
- Delete extremely poor quality. Calliopejen1 (talk) 17:41, 18 December 2011 (UTC)[reply]
- That may be, but at the time during which I uploaded the picture, it was the only picture of Langur mothers with infants on Wikipedia. Unfortunately, I don't have time for extended discussion. Fowler&fowler«Talk» 17:33, 22 December 2011 (UTC)[reply]
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