User:Dockingman/Temp/Ynolate

Source: Wikipedia, the free encyclopedia.

Ynolates are chemical compounds with a negatively charged oxygen attached to an alkyne functionality. [1] They were first synthesized in 1975 by Schöllkopf and Hoppe via the n-butyllithium fragmentation of 3,4-diphenylisoxazole. [2]

Synthetically, they behave as ketene precursors or synthons.

See also

References

  1. ^ Shindo, M. Synthetic uses of ynolates. Tetrahedron 2007, 63, 10.
  2. ^ Schöllkopf, U.; Hoppe, I. Angew. Chem., Int. Ed. Engl. 1975, 14, 765.