User:Dalpoin
In semiconductor, valance bands are well characterised by 3 Luttinger parameters. At Г-point in band structure, and orbitals form valance bands. But spin-orbit coupling splits six fold degeneracy into high energy 4-fold and lower energy 2-fold bands. Again 4-fold degeneracy is lifted into heavy- and light hole bands by phenomenological Hamiltonian by J. M. Luttinger.
Three valance band state
In the presence of spin-orbit interaction, total angular momentum should take part in. From the three valance band, l=1 and s=1/2 state generate six state of |j,mj> as
The spin-orbit interaction from the relativistic quantum mechanics, lowers the energy of j=1/2 states down.
Phenomenological Hamiltonian for the j=3/2 states
Phenomenological Hamiltonian in spherical approximation is written asCite error: The <ref>
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Phenomenological Luttinger parameters are defined as
and
If we take k as k=ke_z, the Hamiltonian is diagonalized for j=3/2 states.
Two degeneated resulting eigenenergies are
for
for
() indicates heav-(light-) hole band energy. If we regard the electrons as nearly free electrons, the Luttinger parameters describe effective mass of electron in each bands.
Measurement of Luttinger parameters
Luttinger parameter can be measured by Hot-electron luminescence experiment.