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A transition metal sulfoxide complex is a coordination complex containing one or more sulfoxide ligands. The inventory is large. The most common sulfoxide...

Sulfoxides, especially DMSO, form coordination complexes with transition metals. Depending on the hard-soft properties of the metal, the sulfoxide binds...

than DIPEA; the pKa values of the respective conjugate acids in dimethyl sulfoxide are 9.0 and 8.5, respectively. Hünig, S.; Kiessel, M. (1958). "Spezifische...

soluble in some organic solvents. These sulfoxide complexes are used in the synthesis of various ruthenium(ii) complexes. They have also attracted attention...

The metal atom usually makes four coordination bonds to the oxygen and nitrogen atoms. The salen anion forms complexes with most transition metals. These...

chemical element with the symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its...

cycle. Sulfoxides and sulfones are thioethers with one and two oxygen atoms attached to the sulfur atom, respectively. The simplest sulfoxide, dimethyl...

widely used as a reagent in organic synthesis and as a ligand for transition metal complexes, including ones that serve as catalysts in organometallic chemistry...

react with the electrophile. The reactions involving charged transition metal complexes (cationic or anionic) are dramatically influenced by solvation...

of the chloro complex [Mo2Cl8]4−. There are a few divalent and trivalent aqua ions of transition metals in the second and third transition series: ruthenium(II)...

based on sodium nitroprusside and the ruthenium sulfoxide compounds. The ruthenium sulfoxide complexes were created and developed by Rack and coworkers...

Fe2(SCH3)2(CO)6. It is a red volatile solid that is classified as a transition metal thiolate complex. It exists as air-stable red crystals with two isomers, where...

terminal vinylidene metal complex chemistry through the dicyanomethylene/oxygen analogy: dicyanovinylidene transition metal complexes". Coordination Chemistry...

The White catalyst is a transition metal coordination complex named after the chemist by whom it was first synthesized, M. Christina White, a professor...

a ligand in organometallic chemistry, giving rise to many transition metal indenyl complexes. Indane Indole Isoindene Indenyl effect Indenone International...

ubiquitous. In all metal aquo-complexes [M(H2O)n]m+, the bonding between water and the metal cation is described as a coordinate covalent bond. Metal-ligand interactions...

coordinating solvents or in the presence of donor ligands. Transition metal carbene complexes of platinum can be prepared by heating platinum bromide with...

organo-transition metal compounds, such as Cu(I) complexes. Along with traditional organic fluorescent molecules and phosphorescent organo-transition metal complexes...

(2010). N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis. Catalysis by Metal Complexes. Vol. 32. Netherlands: Springer. pp. 169–173...

classified as a soft ligand (see also ECW model). It forms complexes with many transition metals but such adducts are often labile. For example, it serves...