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transition metal formyl complex is a metal complex containing one (usually) or more formyl (CHO) ligand. A subset of transition metal acyl complexes,...

Metal carbonyls are coordination complexes of transition metals with carbon monoxide ligands. Metal carbonyls are useful in organic synthesis and as catalysts...

special case are the transition metal formyl complexes. Acyl complexes are usually low-spin and spin-paired. Monometallic acyl complexes adopt one of two...

chain) can be referred to as an aldehyde but can also be classified as a formyl group. Aldehydes are a common motif in many chemicals important in technology...

achieved using transition metal carbonyl complexes including dimanganese decacarbonyl. [C6H5N2]+X− + pinB−Bpin → C6H5Bpin + X−Bpin + N2 A formyl group, –CHO...

3-positions of the chelate rings, giving the corresponding bromo-, nitro-, and formyl-substituted derivatives. Cr(acac)3 is paramagnetic, a property which is...

the formula H2Fe(CO)4. This compound was the first transition metal hydride discovered. The complex is stable at low temperatures but decomposes rapidly...

aldehyde is activated by complexation with the chiral catalyst (R)-BINOL-TiX2 by the formyl lone electron pair syn to the formyl hydrogen to form a pentacoordinate...

low-valent metal centers to give transition metal acyl complexes. Illustrative is the oxidative addition of acetyl chloride to Vaska's complex, converting...

necessary, without the inevitable oxidation (breaking down) of everything. Transition metal ions, due to their multiple oxidation states, were the only elements...

formula Mn2(CO)10, is a binary bimetallic carbonyl complex centered around the first row transition metal manganese. The first reported synthesis of Mn2(CO)10...

preference to the anti isomer; when R2 is the formyl group, the selectivity reverses. Tetralones complexed to chromium may be deprotonated without side...

to any chemical processes in which a compound is functionalized with a formyl group (-CH=O). In organic chemistry, the term is most commonly used with...

products (formyl cation and H2): CH3O+ → H2 + HCO+ Numerous spin-forbidden reactions are encountered in transition metal chemistry since many metal ions can...

carried by adenosine triphosphate the acetyl group, carried by coenzyme A formyl, methenyl or methyl groups, carried by folic acid and the methyl group,...

Longuet-Higgins and Orgel predicted the existence of transition-metal cyclobutadiene complexes, in which the degenerate eg orbital of cyclobutadiene...

alkenes (R2C=CR2). This chemical reaction entails the net addition of a formyl group (−CHO) and a hydrogen atom to a carbon-carbon double bond. This process...

often necessary. The transition metal co-catalyst may server as a "carrier" by first reacting with CO to form a carbonyl complex, which is then transformed...

reaction in which an electron-rich unsaturated hydrocarbon inserts into a formyl C-H bond. With alkenes, the product is a ketone: RCHO + CH2=CHR' → RC(O)CH2CH2R'...

amines to give diimines that are widely studied as binucleating ligands. Formyl groups (aldehydes) are fairly strong deactivating groups for electrophilic...