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chemistry, a transition metal boryl complex is a molecular species with a formally anionic boron center coordinated to a transition metal. They have the...

boryl ligands, like NHC boryl anions, are the most effective ligand in controlling reactivity. Many transition metal boryl complexes have been synthesized...

aromatic. Organometallic compounds with metal-boron bonds (M–BR2) are boryl complexes, corresponding to the notional boryl anion R2B−. Related ligands are borylenes...

reactions proceed via boryl complexes. Bis(pinacolato)diboron can also be used as reducing agent for example in transition metal catalyzed hydrogenations...

diboron tetrafluoride to Vaska's complex was employed to produce an early example of a transition metal boryl complex: 2 B2F4 + IrCl(CO)(PPh3)2 → Ir(BF2)3(CO)(PPh3)2...

00 to 2.15 Å. Boryl complexes have metal-boron bond distances from 2.45 to 2.52 Å, and borane complexes have the largest range of metal-boron bond distances...

wide variety of transition metal alkene complexes (see § Coordination to transition metals), as well as the traditional complexation to the phosphorus...

borylene complex [(OC)5WBN(SiMe3)2] was reported by Holger Braunschweig et al. in 1998. In this compound a borylene is coordinated to a transition metal. Borylenes...

fluorocarbons and nylon, as well as developing transition metal boryl compounds such as boryliridium complexes to facilitate the hydroboration of alkenes...

carbonyls. Transition metal complexes involving 9-borafluorenes include those in which the 9-borafluorene acts as an L-type ligand similar to a metal-boryl complex...

Robins, Warren R. Roper, George R. Whittell, and L. James Wright. "Transition metal− boryl compounds: synthesis, reactivity, and structure." Chemical reviews...

synthesised radical anion lanthanide complexes which also showed antiferromagnetic interaction. The π-acid properties of boryl substituents were employed by...

are provided below. Ion-paired combinations of early and late transition metal complexes can simultaneously interact with a substrate as both Lewis acid...

rhodium dichloride dimer. Strong donor ligands - hydride, silyl, boryl - are required to stabilize Rh(V). This oxidation state is invoked in borylation...

and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E−H Bonds by a Bis(boryl)stannylene". Journal of the American Chemical...

Using FLPs to liberate H2 is metal-free, this is beneficial due to the cost and limited supply of some transition metals commonly used to activate H2...

Metal-catalyzed C–H borylation reactions are transition metal catalyzed organic reactions that produce an organoboron compound through functionalization...

the group have an oxidation state of +2. Nickel is classified as a transition metal with nickel(II) having much chemical behaviour in common with iron(II)...

extraordinarily rare. Strong bases do not deprotonate a borohydride R2BH to the boryl anion R2B−, instead forming the octet-complete adduct R2HB-base. In the...

oxidation to give the hydroboration-oxidation reaction. In this reaction, the boryl group in the generated organoborane is substituted with a hydroxyl group...