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Silylation is the introduction of one or more (usually) substituted silyl groups (R3Si) to a molecule. Silylations are core methods for production of organosilicon...

laboratory glassware, making the surfaces more lipophilic. By the process of silylation, polar functional groups such as alcohols and amines readily undergo reaction...

organosilicon compounds is found to be very efficient and replaced TMSCl reagent. Silylation of glutamic acid with excess hexamethyldisilazane and catalytic TMSCl...

trifluoromethanesulfonic acid. It is commonly used as a Lewis acid catalyst, e.g. in silylations. A white powder, zinc triflate is commercially available, though some...

rn01923. ISBN 9780470842898. Stalling DL, Gehrke CW, Zumwalt RW. A new silylation reagent for amino acids bis(trimethylsilyl)trifluoroacetamide (BSTFA)...

Volumes, vol. 8, p. 616. Kuwajima, I.; Nakamura, E.; Hashimoto, K. (1990). "Silylation of Ketones with Ethyl Trimethylsilacetate: (Z)-3-Trimethylsiloxy-2-Pentene"...

as a result; thus, the development of a one-pot, one-step method for silylation and nucleoside synthesis represented a significant advance. The combination...

deprotection methods are too harsh for the substrate. The mechanism involves silylation of the carbonyl oxygen and elimination of tert-butyl iodide (1), methanolysis...

chloride. Related to its tendency to hydrolyze, TMSOTf is effective for silylation of alcohols: (CH3)3SiO3SCF3 + ROH + Et3N → ROSi(CH3)3Si + [Et3NH]O3SCF3...

which all have an abundance of hydroxyl groups. Silanization differs from silylation, which usually refers to attachment of organosilicon groups to molecular...

Kerry N. Betz, Alexey Fedorov, Brian Stoltz, Robert H. Grubbs (2015). "Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst"...

Enolates can be trapped by the addition of electrophiles at oxygen. Silylation gives silyl enol ether. Acylation gives esters such as vinyl acetate....

("carbodiimide" tautomer). The N≡C–NH2 form dominates, but in a few reactions (e.g. silylation) the diimide form appears to be important. Cyanamide dimerizes to give...

equivalents with silyl halides (typically trimethylsilyl chloride, tmsCl). Silylation of 2-lithio-1,3-dithiane, followed by hydrolysis of the dithioacetal group...

adulteration by added sugars with these methods. Derivatization using silylation reagents is commonly used. Also, the proportions of di- and trisaccharides...

Wilson, Jake W.; Hartwig, John F. (2023). "Transition-Metal-Catalyzed Silylation and Borylation of C–H Bonds for the Synthesis and Functionalization of...

tris(trimethylsilyl)amine plays an important role in the so-called reductive silylation, since it is hydrolyzed with water to ammonia. N 2 + 6 e − → Catalyst...

thermodynamically stable benzylic enolate. Enolates can be trapped by acylation and silylation, which occur at oxygen. Silyl enol ethers are common reagents in organic...

and Grignard reagents with chlorosilanes. In some cases dehydrogenative silylation is another method. Ring, M. A.; O'Neal, H. E.; Rickborn, S. F.; Sawrey...

metathesis Sarett oxidation Sharpless epoxidation Shell higher olefin process Silylation Simmons–Smith reaction Sonogashira coupling Staudinger reaction Stille...