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There is a page named "Reductions with hydrosilanes" on Wikipedia
- Reductions with hydrosilanes are methods used for hydrogenation and hydrogenolysis of organic compounds. The approach is a subset of ionic hydrogenation...13 KB (1,452 words) - 18:38, 26 October 2023
- Hydrosilanes are tetravalent silicon compounds containing one or more Si-H bond. The parent hydrosilane is silane (SiH4). Commonly, hydrosilane refers...8 KB (786 words) - 10:02, 17 May 2023
- Ionic hydrogenation (section Using hydrosilanes)is more electropositive than hydrogen (2.20), hydrosilanes exhibit (mild) hydridic character. Hydrosilanes can serve as hydride donors to highly electrophilic...6 KB (718 words) - 09:08, 28 July 2022
Hydrogenation of carbon–nitrogen double bonds (redirect from Reduction of carbon-nitrogen double bonds)methods have the advantage that they are easy to implement. Reduction with hydrosilanes is a second alternative to transition-metal catalyzed hydrogenation...8 KB (1,016 words) - 00:16, 14 November 2023- Borylation (category Articles with short description)complex reacts with the arene in the catalytic process. A version of the catalytic cycle is shown below for the ortho borylation of hydrosilane compounds....35 KB (3,976 words) - 11:26, 22 April 2024
Organosilicon chemistry (category Articles with short description)hydrosilylation (also called hydrosilation). In this process, compounds with Si-H bonds (hydrosilanes) add to unsaturated substrates. Commercially, the main substrates...25 KB (2,547 words) - 00:08, 6 April 2024
Copper hydride (category Articles with changed ChemSpider identifier)[(Ph3P)CuH]6 (Stryker's reagent) for the reduction of α,β-unsaturated carbonyl compounds. H2 (at least 80 psi) and hydrosilanes can be used as the terminal reductant...23 KB (2,662 words) - 16:50, 28 March 2024
Acenaphthylene (category All articles with unsourced statements)Takasaki, Mikihiro; Nagashima, Hideo (2005). "Catalytic Reduction of Amides to Amines with Hydrosilanes Using a Triruthenium Carbonyl Cluster as the Catalyst"...6 KB (365 words) - 20:41, 25 February 2024
Bis(cyclooctadiene)nickel(0) (category Articles with short description)presence of phosphine ligands catalyzes the demethoxylation of anisoles by hydrosilanes: 2 C6H5OCH3 + [(CH3)2HSi]2O → 2 C6H6 + [(CH3)2(CH3O)Si]2O Wilke, G. (1988)...6 KB (487 words) - 06:33, 20 May 2024
Wilkinson's catalyst (category Articles with short description)Ojima, I.; Kogure, T. (1972). "Selective reduction of α,β-unsaturated terpene carbonyl compounds using hydrosilane-rhodium(I) complex combinations". Tetrahedron...13 KB (1,209 words) - 06:07, 24 February 2024- Germanium dichloride dioxane (category Articles with short description)Bu3SnCl + H2 Hydrosilanes have also been used as reductants. The complex has a polymeric structure. Germanium adopts an SF4-like shape with cis Cl ligands...4 KB (403 words) - 02:21, 12 December 2022
Rhodium (category All articles with dead external links)acid by the Monsanto process. It is also used to catalyze addition of hydrosilanes to molecular double bonds, a process important in manufacture of certain...31 KB (3,674 words) - 22:28, 25 June 2024- Hiyama coupling (category Articles with short description); Hiyama, T. (1988), "Erythro-directive reduction of .alpha.-substituted alkanones by means of hydrosilanes in acidic media", The Journal of Organic...18 KB (1,972 words) - 06:30, 30 June 2023
Hydrocupration (category Articles with short description)alkoxide. The latter species can undergo a final transmetalation with an alkyl hydrosilane (stoichiometric) to regenerate the active ligated copper (I) hydride...14 KB (1,492 words) - 20:58, 3 June 2024
Microcontact printing (category All articles with unsourced statements)a silicone elastomer curing agent. This mixture consists of a short hydrosilane crosslinker that contains a catalyst made from a platinum complex. After...18 KB (2,266 words) - 22:56, 26 February 2024
Organocopper chemistry (category Articles with short description)but catalytic reaction uses copper(I) NHC complex with hydride equivalents provided by a hydrosilane. Generally, the alkylation reaction of organocopper...23 KB (2,439 words) - 16:05, 5 September 2023- Metal carbon dioxide complex (category All articles with unsourced statements)"Copper-Catalyzed Hydrocarboxylation of Alkynes Using Carbon Dioxide and Hydrosilanes". Angewandte Chemie International Edition. 50 (2): 523–527. doi:10.1002/anie...20 KB (2,223 words) - 10:38, 24 August 2023
- reaction between a hydrosilane and the cobalt peroxide adduct leads to a silyl peroxide, which is converted to the alcohol upon reduction, presumably via...18 KB (1,992 words) - 21:40, 7 June 2024
Hypothetical types of biochemistry (category All articles with self-published sources)marinus has been engineered to catalyze new carbon–silicon bonds between hydrosilanes and diazo compounds. Boranes are dangerously explosive in Earth's atmosphere...79 KB (8,177 words) - 12:53, 26 June 2024
Triruthenium dodecacarbonyl (category Articles with short description)Takasaki, Mikihiro; Nagashima, Hideo (2005). "Catalytic Reduction of Amides to Amines with Hydrosilanes Using a Triruthenium Cluster as the Catalyst". Organic...8 KB (769 words) - 14:28, 3 July 2024
- Ojima, T. Kogure (1972). "Selective reduction of α,β-unsaturated terpene carbonyl compounds using hydrosilane-rhodium(I) complex combinations". Tetrahedron