Phosphide bromide
Appearance
Phosphide bromides or bromide phosphides are compounds containing anions composed of bromide (Br−) and phosphide (P3−) anions. Usually phosphorus is covalently connected into more complex structures. They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, phosphide iodides, nitride bromides, arsenide bromides, and antimonide bromides.
List
formula | system | space group | unit cell Å | volume | density | comment | ref |
---|---|---|---|---|---|---|---|
Ca2PBr | cubic | I43d | a=5.96 Z=2 | red brown | [1] | ||
Ca2PBr | hexagonal | R3m | a=4.23 c=20.9 Z=3 | [1] | |||
Cu12P20Br10 | triclinic | P | a = 9.886, b = 13.190, c = 14.763, α = 70.83°, β = 82.68°, γ = 80.13°, Z = 2 | 1786.1 | [2] | ||
Cu13P15Br12 | [3] | ||||||
Cu6PS5Br | cubic | P43m | a=9.732 Z=4 | 921.8 | 4.701 | red | [4] |
(CuBr)2P8Se3 | orthorhombic | Pbcm | a=8.761 b=11.957 c=13.858 Z=4 | 1451.8 | [5] | ||
Sr2PBr | cubic | I43d | a=9.31 Z=2 | brown violet | [1] | ||
Sr2PBr | hexagonal | R3m | a=4.44 c=22.0 Z=3 | dark reddish brown | [1] | ||
Sr2P7Br | cubic | P213 | a=9.789 Z=4 | 938.0 | 3.342 | red band gap 2.1 eV | [6] |
Y2PBr2 | rhombohedral | a=3.9807 c=29.250 | [7] | ||||
Ag6PS5Br | cubic | P43m | a=10.3765 Z=4 | 1117.26 | 5.460 | red | [4] |
Cd5P2Br4 | orthorhombic | Pna21 | a=12.189, b=7.7080, c=13.664 | [8] | |||
Sn24P19.3Br8 | [9] | ||||||
Sn17Zn7P22Br8 | cubic | Pm3n | a=10.7449 | [10] | |||
Sn24−xInxP19.2+0.2x x<16 | cubic | Pm3n | [11] | ||||
Si30+xP16–xTe8–xBrx x = 1–6.4 | cubic | Pm3n | a=9.9720 - 10.0405 | [12] | |||
Ba2PBr | hexagonal | R3m | a=4.67 c=23.3 Z=3 | [1] | |||
Ba2P7Br | monoclinic | P21/m | a=6.294 b=6.835 c=11.850 β=95.819 Z=2 | 507.2 | 3.742 | orange | [13] |
La2PBr2 | trigonal | P3m1 | a=4.311 c=11.000 Z=1 | 177.04 | 5.28 | [7] | |
La3Zn4P6.6Br0.8 | orthorhombic | Cmcm | a=4.099 b=14.229 c=20.388 Z=4 | 1189.0 | 5.290 | black | [14] |
Eu2PBr | R3m | a = 4.385, c = 21.90, Z = 3 | [15] | ||||
W4(PBr)Br10 | monoclinic | C12/m1 | a=14.0933 b=10.3228 c=11.8169 β=93.906 Z=4 | 1715.16 | dark green | [16] | |
Hg2P3Br | orthorhombic | Pbcn | a = 8.014, b = 8.902, c = 7.823, Z = 4 | [17] | |||
Hg7P4Br6 | monoclinic | P21/c | a = 6.0452, b = 19.848, c = 7.5596 β = 104.214° Z=2 | 879.3 | 7.582 | brown | [18] |
(Hg2P)2HgBr4 | monoclinic | P21 | a=7.776 b=12.226 c=7.930 β=121.34 Z=2 | 643.9 | 7.141 | discovered in 1907; bright yellow; air with light sensitive | [19] |
[Hg7P4Br3](SnBr3) | cubic | P213 | a=12.490 Z=4 | [20] |
References
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- ^ a b Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.
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- ^ Hadenfeldt, C.; Held, W. (September 1986). "Darstellung, eigenschaften und kristallstruktur der Europium(ii)-phosphidhalogenide Eu2PCl, Eu2PBr und Eu2PI". Journal of the Less Common Metals (in German). 123 (1–2): 25–35. doi:10.1016/0022-5088(86)90111-6.
- ^ Ströbele, Markus; Eichele, Klaus; Meyer, Hans-Jürgen (2015-02-02). "Cluster Harvesting in the WBr 6 –P System". Inorganic Chemistry. 54 (3): 989–992. doi:10.1021/ic502333u. ISSN 0020-1669. PMID 25392957.
- ^ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (1994-07-01). Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (eds.). "Helical [unk](P 1− ) chains in the structures of Hg 2 P 3 Br and Hg 2 P 3 Cl". Zeitschrift für Kristallographie - Crystalline Materials. 209 (7): 583–585. Bibcode:1994ZK....209..583S. doi:10.1524/zkri.1994.209.7.583. ISSN 2194-4946.
- ^ Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (June 1993). "Syntheses and Crystal Structure of Hg7P4Br6". Journal of Solid State Chemistry. 104 (2): 177–180. Bibcode:1993JSSCh.104..177S. doi:10.1006/jssc.1993.1151.
- ^ Shevelkov, Andrei V.; Mustyakimov, Marat Yu.; Dikarev, Evgeny V.; Popovkin, Boris A. (1996). "(Hg2P)2HgBr4: a phosphorus analogue of the Millon's base salts". Journal of the Chemical Society, Dalton Transactions (1): 147–148. doi:10.1039/dt9960000147. ISSN 0300-9246.
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