Search results

Organoboron chemistry or organoborane chemistry studies organoboron compounds, also called organoboranes. These chemical compounds combine boron and carbon;...

alcohols, amines, or alkyl halides. The most widely known reaction of the organoboranes is oxidation to produce alcohols from alkenes. The development of this...

widely used in Suzuki reaction as an organoborane partner. Aryltrifluoroborate salts are another class of organoboranes that are frequently used because they...

and recipient of the 1979 Nobel Prize in Chemistry for his work with organoboranes. Brown was born Herbert Brovarnik in London, to Ukrainian Jewish immigrants...

Racherla, Uday S. (1992). "Organoboranes for Synthesis. 14. Convenient Procedures for the Direct Oxidation of Organoboranes from Terminal Alkenes to Carboxylic...

toxic if swallowed, with an LD50 of 235 mg/kg in rat test subjects. Organoboranes Pentaborane Zip fuel Brotherton, Robert J.; Weber, C. Joseph; Guibert...

Angeles, California USA Alma mater University of Chicago Known for Organoboranes Awards Tolman Award (1961) Scientific career Fields Chemistry Institutions...

carbon–boron bond, members of this class thus belong to the larger class of organoboranes. Boronic acids act as Lewis acids. Their unique feature is that they...

Richard C.; Brown, Herbert Charles (1970-04-01). "Organoboranes. X. Fast reaction of organoboranes with mercuric acetate. Convenient procedure for the...

regioselectivity is important and often determined by Markovnikov's rule. Organoborane compounds give anti-Markovnikov additions. Electrophilic attack to an...

most studied examples of such Lewis acids are the boron trihalides and organoboranes: BF3 + F− → BF−4 In this adduct, all four fluoride centres (or more...

other things, for the discovery of the nearly quantitative oxidation of organoboranes to alcohols by alkaline hydrogen peroxide. Johnson was Todd Professor...

diethylzinc (Et2Zn), organotin compounds such as tributyltin hydride (Bu3SnH), organoborane compounds such as triethylborane (Et3B), and organoaluminium compounds...

9-Borabicyclo[3.3.1]nonane or 9-BBN is an organoborane compound. This colourless solid is used in organic chemistry as a hydroboration reagent. The compound...

alternatives to boronic acids (RB(OH)2), boronate esters (RB(OR′)2), and organoboranes (R3B), particularly for Suzuki-Miyaura coupling. Boronic acids RB(OH)2...

1975. ISBN 0471112801 Matteson, D. S. Stereodirected Synthesis with Organoboranes, Springer, Berlin, 1995. ISBN 978-3-540-59182-5 Lappert, M. F. (1956)...

bond and carbon-boron bond. The product of carboboration reactions are organoborane compounds which prove to be useful in organic synthesis, containing both...

Karla R. (1996). "A Simple And Convenient Method For The Oxidation Of Organoboranes Using Sodium Perborate: (+)-isopinocampheol". Organic Syntheses. 73:...

Disiamylborane (bis(1,2-dimethylpropyl)borane) is an organoborane with the formula [((CH3)2CHCH(CH3))2BH]2 (abbreviation: Sia2BH). It is a colorless waxy...

hydroboration-oxidation reaction. In this reaction, the boryl group in the generated organoborane is substituted with a hydroxyl group. Phosphine-boranes, with the formula...