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The inverse electron demand Diels–Alder reaction, or DAINV or IEDDA is an organic chemical reaction, in which two new chemical bonds and a six-membered...

substituents on the two components. In an inverse (reverse) electron-demand Diels–Alder reaction, electron-withdrawing substituents on the diene lower...

including the inverse electron-demand Diels–Alder reaction, Hexadehydro Diels-Alder reaction and the related alkyne trimerisation. The reaction can also be...

referred to simply as Click reactions Thiol-ene reaction Diels-Alder reaction and inverse electron demand Diels-Alder reaction [4+1] cycloadditions between...

The 1,2,4-triazines can react with electron-rich dienophiles in an inverse electron demand Diels-Alder reaction. This forms a bicyclic intermediate which...

than the electron-poor tetrachloroethene (see reactivity scale below). This type resembles the inverse electron-demand Diels-Alder reaction, in which...

(no. 5 in the Rawal synthesis). The key step was an inverse electron demand Diels–Alder reaction of cyclophane 1 by heating in N,N-diethylaniline (dinitrogen...

SnCl4, AlCl3, and MeAlCl2 can catalyze both normal and inverse electron demand Diels-Alder reactions. The enhancement in rate is often dramatic, and regioselectivity...

Boger, who first reported it in 1981. The reaction is a form of inverse-electron demand Diels-Alder reaction in which an enamine reacts with a 1,2,4-triazine...

synthesized from 2-hydroxy-4-methoxybenzaldehyde using the inverse electron-demand Diels–Alder reaction. Vanillin 2-Hydroxy-5-methoxybenzaldehyde Isovanillin...

immonium diene in an Inverse electron-demand Diels–Alder reaction. Researchers have extended the Grieco three-component reaction to reactants or catalysts...

high temperatures and reduced pressure. First an inverse-electron-demand hetero-Diels-Alder reaction occurred to give intermediate 45. Thermodynamically...

electronic demand for the Diels–Alder reaction calls for an electron-rich diene to react with an electron-poor olefin (or "dienophile"), while the inverse electron-demand...

Other authors have used it in inverse-electron-demand Diels–Alder reactions leading to sesquiterpene dimers or in reactions forming simple derivatives....

symmetric, meaning the reaction between these species is allowed as well. This is referred to as the "inverse electron demand Diels–Alder." A sigmatropic rearrangement...

is the reaction of a trans-cyclooctene and an s-tetrazine in an inverse-demand Diels Alder reaction followed by a retro-Diels Alder reaction to eliminate...

pyridopyridazines via a diene-transmissive Diels–Alder reaction involving inverse electron-demand hetero Diels–Alder cycloaddition of cross-conjugated azatrienes...

(2008). "The Tetrazine Ligation: Fast Bioconjugation based on Inverse-electron-demand Diels-Alder Reactivity". Journal of the American Chemical Society. 130...

Hartmann and Heuschmann: Isolation of a Zwitterion in a Diels–Alder Reaction with Inverse Electron Demand; Angewandte Chemie; september 1989; Volume 28, Issue...

electrophiles such as Bronsted acids. Similarly, they undergo inverse demand Diels-Alder reactions. The reactivity of enol ethers is highly dependent on the...