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Bis[(2-diphenylphosphino)phenyl] ether, also known as DPEphos, is a wide bite angle diphosphine ligand used in inorganic and organometallic chemistry. The name DPEphos...

generally to any chelating ligand, it is commonly applied to describe diphosphine ligands, as they can adopt a wide range of bite angles. Diamines form...

Diphosphane, or diphosphine, is an inorganic compound with the chemical formula P2H4. This colourless liquid is one of several binary phosphorus hydrides...

Diphosphines, sometimes called bisphosphanes, are organophosphorus compounds most commonly used as bidentate phosphine ligands in inorganic and organometallic...

2′-bis(diphenylphosphino)-1,1′-binaphthyl) is an organophosphorus compound. This chiral diphosphine ligand is widely used in asymmetric synthesis. It consists of a pair...

compound derived from the heterocycle xanthene. It is used as a bidentate diphosphine ligand and is noteworthy for having a particularly wide bite angle (108°)...

Phosphines of a more specialized nature are usually prepared by other routes. Diphosphines are also available in primary, secondary, and tertiary phosphorus substituents...

properties of diphosphines makes them especially useful in asymmetric catalysis, e.g. Noyori asymmetric hydrogenation. Several diphosphines have been developed...

Alkynylpalladium(IV) and -Platinum(IV) Species, Including Triorgano(diphosphine)metal(IV) Complexes and the Structural Study of an Alkynyl(pincer)platinum(IV)...

one of the first demonstrations of the Kumada coupling using nickel diphosphine catalysts. This mild and efficient process contrasted with older methods...

A Josiphos ligand is a type of chiral diphosphine which has been modified to be substrate-specific; they are widely used for enantioselective synthesis...

phosphorus atoms and have the formula PnHn+2. The highly flammable gas diphosphine (P2H4) is an analogue of hydrazine. Compounds with P-C and P-O-C bonds...

advances. Henri Kagan developed DIOP, an easily prepared C2-symmetric diphosphine that gave high ee's in certain reactions. Ryōji Noyori introduced the...

yields chirality in the reaction product. An early C2-symmetric ligand, diphosphine catalytic ligand DIPAMP, was developed in 1968 by William S. Knowles...

compound having the chemical formula HP(PH2)2. It can be generated from diphosphine but is highly unstable at room temperature: 2 P2H4 → P3H5 + PH3 Samples...

Daniel L. DuBois on mechanistic studies of H2 oxidation with nickel bis(diphosphine) complexes. In 2009, she was hired as a senior staff scientist at PNNL...

coordination complex with the formula NiCl2(dppe); where dppe is the diphosphine 1,2-bis(diphenylphosphino)ethane. It is used as a reagent and as a catalyst...

a ferrocene moiety in its backbone, and is related to other bridged diphosphines such as 1,2-bis(diphenylphosphino)ethane (dppe). This compound is commercially...

form polymers; a few exceptions exist, such as the near-tetrahedral diphosphine and diarsine complexes [Ag(L–L)2]+. Under standard conditions, silver...

containing phosphine ligands as the spectator ligands. Many of these diphosphine ligands, such as BINAP, contain arene rings and impart chirality from...