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In stereochemistry, a chiral auxiliary is a stereogenic group or unit that is temporarily incorporated into an organic compound in order to control the...

synthesis. The chiral metal catalysts are almost invariably rendered chiral by using chiral ligands, but it is possible to generate chiral-at-metal complexes...

from other reagents or catalysts present in the reaction. This allows spatial information (what chemists refer to as chirality) to transfer from one molecule...

In the absence of an effective enantiomeric environment (precursor, chiral catalyst, or kinetic resolution), separation of a racemic mixture into its enantiomeric...

can be effected using thiourea-derived catalysts. In 2012, a BINOL-derived catalyst was employed to generate chiral cyanide anion (see figure). The German...

reaction with a chiral catalyst or reagent, resulting in an enantioenriched sample of the less reactive enantiomer. As opposed to chiral resolution, kinetic...

Rhodium catalysts are also used to reduce benzene to cyclohexane. The complex of a rhodium ion with BINAP is a widely used chiral catalyst for chiral synthesis...

resolution, in which a pre-existing chiral center undergoes reaction with a chiral catalyst, an enzyme or a chiral reagent such that one enantiomer reacts...

the active catalyst is not known, Corey’s model proposes the following: the aldehyde is activated by complexation with the chiral catalyst (R)-BINOL-TiX2...

A variety of chiral thiourea catalysts are under investigation for asymmetric MBH reactions. Chiral thiourea and bis(thiourea) catalysts can be effective...

reagents. Without a chiral influence (for example a chiral catalyst, solvent or starting material), a chemical reaction that makes a chiral product will always...

1021/ar960061v. PMID 10891060. Yoon, TP; Jacobsen, EN (2003). "Privileged Chiral Catalysts". Science. 299 (5613): 1691–1693. doi:10.1126/science.1083622. PMID 12637734...

acids have been used as catalyst for the modification of cellulose in water on multi-ton scale. When the organocatalyst is chiral an avenue is opened to...

"interiors" containing the ion and a hydrophobic exterior. Chiral phase-transfer catalysts have also been demonstrated. PTC is widely exploited industrially...

enantiopurity of the catalyst or chiral auxiliary does not correspond with the enantiopurity of the product produced. For example: a racemic catalyst would be expected...

Such chiral diols are important in organic synthesis. The introduction of chirality into nonchiral reactants through usage of chiral catalysts is an...

may be hydrogenated with low enantioselectivity in the presence of a chiral catalyst. Additionally, the substituent attached to nitrogen affects both the...

Proline, a naturally occurring chiral compound, is readily and cheaply available. It transfers its stereocenter to the catalyst which in turn is able to drive...

product might deactivate the catalyst. Acyclic imines have E/Z isomers. This makes it difficult to create enantiopure chiral compounds through stereoselective...

mechanisms of each of these reactions differ somewhat, in each case the chiral catalyst or reagent must be involved in the enantio determining conjugate addition...