Draft:Molecular-strain engineering: Difference between revisions

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{{AFC submission|d|context|u=Ll0103|ns=118|decliner=Raydann|declinets=20230113215338|ts=20221119090434}} <!-- Do not remove this line! -->
{{Short description|Strain engineering in molecules}}
{{AFC submission|d|context|u=Ll0103|ns=118|decliner=CodeLyoko|declinets=20221108033303|small=yes|ts=20221107124232}} <!-- Do not remove this line! -->
{{Draft topics|stem}}
{{AfC topic|stem}}
{{AfC submission|||ts=20221119090434|u=Ll0103|ns=118}}
{{AFC submission|d|context|u=Ll0103|ns=118|decliner=CodeLyoko|declinets=20221108033303|ts=20221107124232}} <!-- Do not remove this line! -->
{{AFC submission|d|reason|I'm struggling with this. You have added a small amount of material since asked to produce more information, but I am failing to see even a stub article here, the minimum standard for acceptance.
{{AFC submission|d|reason|I'm struggling with this. You have added a small amount of material since asked to produce more information, but I am failing to see even a stub article here, the minimum standard for acceptance.


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So where do you go from here? Improved content and, ideally, more substantial coverage ''about'' the topic. We also need the reader to know what the topic is about in words for the generalist reader, and this should happen in the lead section.|u=Ll0103|ns=118|decliner=Timtrent|declinets=20221008201321|small=yes|ts=20220602061106}} <!-- Do not remove this line! -->
So where do you go from here? Improved content and, ideally, more substantial coverage ''about'' the topic. We also need the reader to know what the topic is about in words for the generalist reader, and this should happen in the lead section.|u=Ll0103|ns=118|decliner=Timtrent|declinets=20221008201321|small=yes|ts=20220602061106}} <!-- Do not remove this line! -->
{{AFC submission|d|mergeto|u=Ll0103|ns=118|decliner=HenryTemplo|declinets=20220523105016|small=yes|ts=20220523033617}} <!-- Do not remove this line! -->
{{AFC submission|d|mergeto|u=Ll0103|ns=118|decliner=HenryTemplo|declinets=20220523105016|small=yes|ts=20220523033617}} <!-- Do not remove this line! -->

{{AFC comment|1=Please see [[WP:TECHNICAL]] <b><span style="background:#444;padding:2px 12px;font-size:12px"><span style="color:#FC0">❯❯❯</span>[[User:Raydann|<span style="color:#fff"> Raydann</span>]][[User talk:Raydann|<sup><i><span style="color:#D3D3D3">(Talk)</span></i></sup>]]</span></b> 21:53, 13 January 2023 (UTC)}}


{{AFC comment|1=I agree with the other editors here, without context or many references and with how short this article is, I don't think it has substantial coverage for an article yet <span style= "font-weight: bold;">[[User:CodeLyoko|<span style="color:#800000">CodeLyoko</span>]]</span><sup>[[User talk:CodeLyoko|talk]]</sup> 03:33, 8 November 2022 (UTC)}}
{{AFC comment|1=I agree with the other editors here, without context or many references and with how short this article is, I don't think it has substantial coverage for an article yet <span style= "font-weight: bold;">[[User:CodeLyoko|<span style="color:#800000">CodeLyoko</span>]]</span><sup>[[User talk:CodeLyoko|talk]]</sup> 03:33, 8 November 2022 (UTC)}}
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{{Short description|Strain engineering in molecules}}

{{Draft topics|stem}}
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{{Underlinked|date=October 2022}}
{{Underlinked|date=October 2022}}
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3.1 Mechanically tuning [[spin crossover]] property within [[molecular knot]]s.<ref name="Liu2022-2">{{cite journal|last1=Wu|first1=L|last2=Tang|first2=M|last3=Jiang|first3=L|last4=Chen|first4=Y|last5=Bian|first5=L|last6=Liu|first6=J|last7=Wang|first7=S|last8=Liang|first8=Y|last9=Liu|first9=Z|year=2022|title=Synthesis of contra-helical trefoil knots with mechanically tuneable spin-crossover properties|journal=Nature Synthesis|volume=1|pages= |issn=2468-5194|doi=10.1038/s44160-022-00173-7|s2cid=253054404}}</ref>
3.1 Mechanically tuning [[spin crossover]] property within [[molecular knot]]s.<ref name="Liu2022-2">{{cite journal|last1=Wu|first1=L|last2=Tang|first2=M|last3=Jiang|first3=L|last4=Chen|first4=Y|last5=Bian|first5=L|last6=Liu|first6=J|last7=Wang|first7=S|last8=Liang|first8=Y|last9=Liu|first9=Z|year=2022|title=Synthesis of contra-helical trefoil knots with mechanically tuneable spin-crossover properties|journal=Nature Synthesis|volume=1|pages= |issn=2468-5194|doi=10.1038/s44160-022-00173-7|s2cid=253054404}}</ref>


3.2 Tuning photophysical properties by varying intramolecular strain.<ref name="Gryko2022">{{cite journal|last1=Sadowski|first1=Bartłomiej|last2=Mierzwa|first2=Dominik|last3=Kang|first3=Seongsoo|last4=Grzybowski|first4=Marek|last5=Poronik|first5=Yevgen M.|last6=Sobolewski|first6=Andrzej L.|last7=Kim|first7=Dongho|last8=Gryko|first8=Daniel T.|year=2022|title=Tuning the aromatic backbone twist in dipyrrolonaphthyridinediones|journal=Chemical Communications|volume=58|issue=22 |pages= 3697–3700|issn=1359-7345|doi=10.1039/D1CC06863F|pmid=35225999 |s2cid=247046640 }}</ref>
3.2 Tuning photophysical properties by varying intramolecular strain.<ref name="Gryko2022">{{cite journal|last1=Sadowski|first1=Bartłomiej|last2=Mierzwa|first2=Dominik|last3=Kang|first3=Seongsoo|last4=Grzybowski|first4=Marek|last5=Poronik|first5=Yevgen M.|last6=Sobolewski|first6=Andrzej L.|last7=Kim|first7=Dongho|last8=Gryko|first8=Daniel T.|year=2022|title=Tuning the aromatic backbone twist in dipyrrolonaphthyridinediones|journal=Chemical Communications|volume=58|issue=22 |pages= 3697–3700|issn=1359-7345|doi=10.1039/D1CC06863F|pmid=35225999 |s2cid=247046640 }}</ref>


3.3 Strain-induced enhancement in reactivity of molecules.<ref name="Ito2022">{{cite journal|last1=Zhang|first1=Xinjiang|last2=Mackinnon|first2=Marc R.|last3=Bodwell|first3=Graham J.|last4=Ito|first4=Shingo|year=2022|title=Synthesis of a π-Extended Azacorannulenophane Enabled by Strain-Induced 1,3-Dipolar Cycloaddition|journal=Angewandte Chemie International Edition|volume=61|issue=16 |pages=e202116585|issn=1521-3773|doi=10.1002/anie.202116585|pmid=35148448 |s2cid=246776573 }}</ref>
3.3 Strain-induced enhancement in reactivity of molecules.<ref name="Ito2022">{{cite journal|last1=Zhang|first1=Xinjiang|last2=Mackinnon|first2=Marc R.|last3=Bodwell|first3=Graham J.|last4=Ito|first4=Shingo|year=2022|title=Synthesis of a π-Extended Azacorannulenophane Enabled by Strain-Induced 1,3-Dipolar Cycloaddition|journal=Angewandte Chemie International Edition|volume=61|issue=16 |pages=e202116585|issn=1521-3773|doi=10.1002/anie.202116585|pmid=35148448 |s2cid=246776573 }}</ref>


== References ==
== References ==

Revision as of 21:53, 13 January 2023

  • Comment: I agree with the other editors here, without context or many references and with how short this article is, I don't think it has substantial coverage for an article yet CodeLyokotalk 03:33, 8 November 2022 (UTC)
  • Comment: You have resubmitted this without doing the work required. Please actually read and understand prior reviews and act on them of you wish this to have a chance of acceptance 🇺🇦 FiddleTimtrent FaddleTalk to me 🇺🇦 12:52, 7 November 2022 (UTC)
  • Comment: As Timtrent mentioned before, there is a very small amount of content on this submission. The citations are reliable but I struggle to see notability on this one. Perhaps elaborating on the topic more may be a good idea. Eternal Shadow Talk 04:20, 10 October 2022 (UTC)

Molecular-strain engineering(MSE) implies using strain to impose intramolecular tension on molecules, which, owing to their precisely tunable strained conformations, can exhibit enhanced performance in certain situations, such as the control of assembly processes,[1] modulation of their own properties, and manipulation of reaction progress and selectivities.[2][3] The MSE strategy are currently applied in three aspects: (1) The modulation of assembly processes by precisely tuning conformations of building blocks using intramolecular strain; (2) Manipulation of reaction progress and selectivities by employing intramolecular strain to tuning the reaction energy diagram; (3) Modulation of the physical and chemical properties of molecules by tuning the basic geometrical parameters such as bond length and valence angle with strain. MSE aims to gain insight into the modulation mechanisms and rules of mechanical strain on molecular behaviors and properties.

1. The control of supramolecular assembly processes by MSE.

  1.1 Molecular-strain engineering of double-walled tetrahedra.[1]
  1.2 Tuning atropisomeric conversion in supramolecular structure.[4]

2. Manipulation of reaction progress and selectivities by MSE.

  2.1 Mechanical trapping of the phlorin intermediate.[2]
  2.2 Mechanical trapping and in situ derivatization of the porphodimethene intermediate.[3]
  2.3 Tunable force-directed bond cleavage strategy by MSE.[5]

3. Modulation of physical and chemical properties of molecules by MSE.

  3.1 Mechanically tuning spin crossover property within molecular knots.[6]
  3.2 Tuning photophysical properties by varying intramolecular strain.[7]
  3.3 Strain-induced enhancement in reactivity of molecules.[8]

References

  1. ^ a b Tang, M; Liang, Y; Lu, X; Miao, X; Jiang, L; Liu, J; Bian, L; Wang, S; Wu, L; Liu, Z (2021). "Molecular-strain engineering of double-walled tetrahedra". Chem. 7 (8): 2160–2174. doi:10.1016/j.chempr.2021.05.004. ISSN 2451-9294. S2CID 236307165.
  2. ^ a b Tang, M; Liang, Y; Liu, J; Bian, L; Liu, Z (2022). "Mechanical trapping of the phlorin intermediate". CCS Chemistry. 4 (10): 3230–3237. doi:10.31635/ccschem.022.202101679. ISSN 2096-5745. S2CID 246857591.
  3. ^ a b Tang, M; Liang, Y; Liu, J; Wu, L; Wang, S; Bian, L; Jiang, L; Tang, Z-B; Liu, Z (2022). "Mechanical trapping and in situ derivatization of the porphodimethene intermediate". Materials Today Chemistry. 24: 100868. doi:10.1016/j.mtchem.2022.100868. ISSN 2468-5194. S2CID 247902967.
  4. ^ Norvaiša, K; Maguire, S; Donohoe, C; O'Brien, JE; Twamley, B; Gomes-da-Silva, LC; Senge, MO (2021). "Steric Repulsion Induced Conformational Switch in Supramolecular Structures". Chemistry–A European Journal. 28 (4): e202103879. doi:10.1002/chem.202103879. ISSN 1521-3765. PMC 9299809. PMID 34792217.
  5. ^ Ma, W; Cheng, T; Liu, F-Z; Liu, Y; Yan, KK (2022). "Allosteric Binding-Induced Intramolecular Mechanical-Strain Engineering". Angewandte Chemie International Edition. 61 (18): e202202213. doi:10.1002/anie.202202213. ISSN 1521-3773. PMID 35212101. S2CID 247108052.
  6. ^ Wu, L; Tang, M; Jiang, L; Chen, Y; Bian, L; Liu, J; Wang, S; Liang, Y; Liu, Z (2022). "Synthesis of contra-helical trefoil knots with mechanically tuneable spin-crossover properties". Nature Synthesis. 1. doi:10.1038/s44160-022-00173-7. ISSN 2468-5194. S2CID 253054404.
  7. ^ Sadowski, Bartłomiej; Mierzwa, Dominik; Kang, Seongsoo; Grzybowski, Marek; Poronik, Yevgen M.; Sobolewski, Andrzej L.; Kim, Dongho; Gryko, Daniel T. (2022). "Tuning the aromatic backbone twist in dipyrrolonaphthyridinediones". Chemical Communications. 58 (22): 3697–3700. doi:10.1039/D1CC06863F. ISSN 1359-7345. PMID 35225999. S2CID 247046640.
  8. ^ Zhang, Xinjiang; Mackinnon, Marc R.; Bodwell, Graham J.; Ito, Shingo (2022). "Synthesis of a π-Extended Azacorannulenophane Enabled by Strain-Induced 1,3-Dipolar Cycloaddition". Angewandte Chemie International Edition. 61 (16): e202116585. doi:10.1002/anie.202116585. ISSN 1521-3773. PMID 35148448. S2CID 246776573.