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An allylic rearrangement or allylic shift is an organic chemical reaction in which reaction at a center vicinal to a double bond causes the double bond...

The Tsuji–Trost reaction (also called the Trost allylic alkylation or allylic alkylation) is a palladium-catalysed substitution reaction involving a substrate...

that involves a nucleophilic substitution reaction combined with an allylic shift in a glycal (a 2,3-unsaturated glycoside). It was discovered by the...

allylboration, an allylborane adds across an aldehyde or ketone with an allylic shift, and can then be converted to a homoallylic alcohol during workup. The...

the olefin, followed by oxidative addition at the γ position and an allylic shift to displace the leaving group. This generates a Cu(III) allyl complex...

Allylic strain (also known as A1,3 strain, 1,3-allylic strain, or A-strain) in organic chemistry is a type of strain energy resulting from the interaction...

product. Allylic oxidation using selenium-dioxide proceeds via an ene reaction at the electrophilic selenium center. A 2,3-sigmatropic shift, proceeding...

nucleophilic attack of the chlorochromate by the allylic alcohol. The ester then undergoes a [3,3]-sigmatropic shift to create the isomeric chromate ester (2)...

shift then takes place to give a more stable allylic carbocation. The final step in the formation of zingiberene is the removal of the cyclic allylic...

transformation of an allyl alkoxy silyl to an allyl alcohol without an allylic shift. In their report, the chemists observed that the hydroxyl group was...

ene double bond and 1,5 hydrogen shift. The product is a substituted alkene with the double bond shifted to the allylic position. This transformation is...

Palladium-Catalyzed Allylic Substitutions with Phosphinooxazoline (PHOX) Ligands by Hammett and Swain–Lupton Analysis of the 13C NMR Chemical Shifts of the (π-Allyl)palladium...

rearrangements and can be classified into two types. Rearrangements of allylic sulfoxides, amine oxides, selenoxides are neutral. Rearrangements of carbanions...

iridium catalysts with (R,R,R)-phosphoramidite L The allylic aminations of a wide variety of achiral allylic esters proceeded with total conversion and superb...

the carbon–carbon pi-bond and the presence of allylic CH centers. The former dominates but the allylic sites are important too. Hydrogenation involves...

different conformations. Allylic strain, or A1,3 strain is closely associated to syn-pentane strain. An example of allylic strain can be seen in the...

undergoes cyclization to form a menthyl cationic species. A hydride shift then forms an allylic carbocation. Finally, an elimination reaction occurs at one of...

rearrangement reaction, although these are not necessarily realistic. In allylic rearrangement, the reaction is indeed ionic. Three key rearrangement reactions...

alkanes, this method is inexpensive but not selective enough to be useful. Allylic and benzylic compounds undergo more selective oxidations. Alkyl groups...

olefin. Pd(0) intermediates are implicated. 1973 - The Trost asymmetric allylic alkylation is a nucleophilic substitution. 1975 - The Sonogashira coupling...